Pr. Abderrahmane AMGOUNE
Professeur Université Claude Bernard, Lyon 1
Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, UMR 5246
email : abderrahmane.amgoune[at]univ-lyon1.fr
Sept 2017- Full Professor, ICBMS UMR 5246, University Claude Bernard Lyon 1, Lyon
Avril 2014 Habilitation à diriger les recherches, University Paul Sabatier, Toulouse
2012-2017 CNRS research scientist CR1, UMR 5069 LHFA, Toulouse
2008-2012 CNRS research scientist CR2, UMR 5069 LHFA, Toulouse
2006-2008 Post-doctoral fellow at Universitat Konstanz, Germany. Alexander von Humboldt Fellowship with Pr. Dr. Stefan Mecking
“Design of new group 8-10 complexes for olefin polymerization catalysis”
2003-2006 PhD in chemistry, with honours at University of Rennes 1, Rennes
Supervisors : Prof. J.-F ; Carpentier and Dr. Christophe Thomas
“New group 3 organometallic complexes for ring-opening polymerization of lactones and lactides.”
2002-2003 Master II in Organic Chemistry, at University of Lyon 1
Awards & Honors
2016 Nomination as distinguished junior member of the French Chemical Society (member distingué Junior 2016 de la SCF)
2016 Young Investigator Award from the French Chemical Society, Organic chemistry division (Prix Jeune chercheur 2016 de la division de chimie organique de la SCF)
2012–2016 CNRS Excellence scientific Award in chemistry from the CNRS
2012 Young Investigator Award from the chemistry institute of Toulouse
2006–2008 Alexander von Humboldt Scholarship, Universitat Konstanz, Konstanz, Germany.
2006 Award of the best PhD thesis of University Rennes 1, (France).
Scientific production (see publication list)
49 Publications (11 Angew. Chem. Int. Ed., 8 J. Am. Chem. Soc., 1 Nature Commun. 1 Chem Sci, 4 Chem. Commun., 2 Chem. Eur. J., 7 Organometallics, 1 invitation dans Org. Chem. Front., 2 book chapters), 3 patents. h-index : 24
Organometallic chemistry and homogeneous catalysis
Keywords : Ligand design, well-defined complexes, gold, mechanistic studies, sigma-bond activation (C-O, C-N, C-H bond activation), applications in organic synthesis (cross coupling) and biodegradable polymers.
Research overview :
Au(I)/Au(III) catalysis : (collab. with D. Bourissou, Toulouse and K. Miqueu, Pau)
We are develloping new catalytic transformations with gold, such as direct arylation processes, hydrofunctionalization of olefins, and C-X (X= O, N, C, S…) cross coupling reactions. We are also getting interested in the preparation and isolation of high valent gold and copper species (+III oxidation state) for C–H activation and olefin insertion processes.
C-O and C-N bond activation :
We are exploring new catalytic strategies for the atom-economic coupling of C-O and C-N based electrophiles building with a large scope of nucleophiles (including very mild nucleophilic partners C-H bond activation) as well as possible further functionalization reactions. We are particularly investigating new cooperative strategy that rely on the combination of purposely designed first row transition metal based catalysts with electrophilic partners.