C(sp³)–H Bond Acylation with N-Acyl-imides under Photoredox/Nickel Dual Catalysis
Taline Kerackian, Antonio Reina, Tetiana Krachko, Hugo Bodaert, Didier Bouyssi, Nuno Monteiro, Abderrahmane Amgoune
Synlett 2020, Accepted. (Invited contribution for Synlett cluster in Modern nickel catalyzed processes)

Nickel-Catalyzed Mono-Selective a-Arylation of Acetone with Aryl Chlorides and Phenol Derivatives
S. Abou Derhamine, T. Krachko, N. Monteiro, G. Pilet, J. Schranck, A. Tlili, A. Amgoune
Angew. Chem., Int. Ed., 2020, doi.org/10.1002/anie.202006826 (Hot Paper)

Gold(I)/Gold(III) Catalysis that Merges Oxidative Addition and p -Alkene Activation
M. Rigoulet, O. Thillaye du Boullay, A. Amgoune, D. Bourissou
Angew. Chem., Int. Ed., 2020, doi.org/10.1002/anie.202006074

Development and Mechanistic Investigations of a Base-Free Suzuki-Miyaura Cross-Coupling of a,a-Difluoroacetamides via C–N Bond Cleavage.
Antonio Reina, Tetiana Krachko, Killian Onida, Didier Bouyssi, Erwann Jeanneau, Nuno Monteiro, and Abderrahmane Amgoune
ACS Catal. 2020, 10, 2189-2197.

Silyl radical mediated cross-electrophile coupling of N-acyl-imides with alkyl bromides under photoredox/nickel dual catalysis
Taline Kerackian, Antonio Reina, Didier Bouyssi, Nuno Monteiro, Abderrahmane Amgoune
Org. Lett. 2020, 22, 2240-2245. 

Solvent-free direct α-alkylation of ketones by alcohols catalyzed by nickel supported on silica-alumina.
Charvieux, A.; Giorgi, J. B.; Duguet, N.; Métay, E. Green Chem. 2018, 20, 4210–4216.
DOI: 10.1039/c8gc01958d

Reduction of aromatic nitriles into aldehydes using calcium hypophosphite and a nickel precursor.
Mouselmani, R.; Hachem, A.; Alaaeddine, A.; Métay, E.; Lemaire, M. Org. Biomol. Chem. 2018, 16, 6600–6605.
DOI: 10.1039/c8ob01751d

A Two-Step Oxidative Cleavage of 1,2-Diol Fatty Esters into Acids or Nitriles by a Dehydrogenation–Oxidative Cleavage Sequence.
Guicheret, B.; Bertholo, Y.; Blach, P.; Raoul, Y.; Métay, E.; Lemaire, M. ChemSusChem 2018, 11, 3431-3437.
DOI: 10.1002/cssc.201801640

Direct aldolization of unprotected fructose to bio-based surfactants.
Zhu, B.; Chen, G.-R.; Duguet, N.; Lemaire, M. ACS Sustainable Chem. Eng. 2018, 6, 11695-11703.
DOI: 10.1021/acssuschemeng.8b01953

Robust organocatalysts for the cleavage of vegetable oil derivatives to aldehydes through retro-benzoin condensation.
Vu, N. D.; Bah, S.; Deruer, E.; Duguet, N.; Lemaire, M. Chem. – Eur. J. 2018, 24, 8141-8150.
DOI: 10.1002/chem.201800091

Sucres et huiles : des ingrédients clés pour la chimie biosourcée (Sugars and oils: key ingredients for bio-based chemistry).
Duguet, N.; Métay, E.; Lemaire, M.; Moebs-Sanchez, S.; Ahmar, M.; Popowycz, F.; Queneau, Y. Actualité Chimique 2018, 427-428, 39-45.
Link

Preparation of para-Aminophenol from Nitrobenzene through Bamberger Rearrangement Using a Mixture of Heterogeneous and Homogeneous Acid Catalysts.
Joncour, R.; Ferreira, A.; Duguet, N.; Lemaire, M. Org. Process Res. Dev. 2018, 2018, 22, 312−320.
DOI: 10.1021/acs.oprd.7b00354

Trialkylamine-Catalyzed Aldolization of Unprotected 1,3-Dihydroxyacetone (DHA) toward C-C Bond-Linked Tetraol Surfactants.
Zhu, B.; Belmessieri, D.; Ontiveros, J. F.; Aubry, J.-M.; Chen, G.-R.; Duguet, N.; Lemaire, M. ACS Sustainable Chem. Eng. 2018, 6, 2630−2640.
DOI: 10.1021/acssuschemeng.7b04135

Methylation of Polyols with Trimethylphosphate in the Presence of a Lewis or Bronsted Acid Catalyst.
Duclos, M.-C.; Herbinski, A.; Mora, A.-S.; Metay, E.; Lemaire, M. ChemSusChem 2018, 11, 547-551.
DOI: 10.1002/cssc.201701841

An eco-compatible pathway to new hydrotropes from tetraols.Herbinski, A.; Metay, E.; Da Silva, E.; Illous, E.; Aubry, J.-M.; Lemaire, M. Green Chem. 2018, 20, 1250–1261.
DOI: 10.1039/c7gc02990j

Preparation and Catalytic Properties of Various Oxides and Mesoporous Materials Containing Niobium and Sulfate Ions, in the Etherification Reaction of 2-Naphtol.
Hussein, A. H.; Nahas, H.; Jahjah, M.; Srour, M.; Jahjah, R.; Duguet, N.; Lemaire, M.; Naoufal, D. Int. J. Org. Chem. 2018, 8, 16-40.
DOI: 10.4236/ijoc.2018.81002

Catalytic Properties of Various Oxides and Mesoporous Materials Containing Niobium and Sulfate Ions, in the Oxidation Reaction of 1-Octanol.
Hussein, A. H.; Khalil, A.; Jahjah, M.; Srour, M.; Jahjah, R.; Duguet, N.; Lemaire, M.; Naoufal, D. Int. J. Org. Chem. 2018, 8, 41-53.
DOI: 10.4236/ijoc.2018.81003

Nouveaux outils synthétiques pour une chimie respectueuse de l’environnement.
Métay, E. Actualité Chimique, 2017, 424, 50-55.
Link

Dodecyl sorbitan ethers as antimicrobials against Gram-positive bacteria.
Belmessieri, D.; Gozlan, C.; Duclos, M.-C.; Dumitrescu, O.; Lina, G.; Redl, A.; Duguet, N.; Lemaire, M. Bioorg. Med. Chem. Lett. 2017, 27, 4660-4663.
DOI: 10.1016/j.bmcl.2017.09.015

Chiral N-arylated diamine – Copper complexes catalyzed asymmetric Henry reaction
El-Asaad, B.; Metay, E.; karame, I.; Lemaire, M. Mol. Catal., 2017, 435, 76-81.
DOI: 10.1016/j.mcat.2017.03.017

New insights into the catalytic reduction of aliphatic nitro compounds with hypophosphites under ultrasonic irradiation
Letort, S.; Lejeune, M.; Kardos, N.; Metay, E.; Popowycz, F.; Lemaire, M.; Draye, M. Green Chem., 2017, 19, 4583-4590.
DOI: 10.1039/c7gc01622k

Homogeneous and Heterogeneous Catalytic (Dehydrogenative) Oxidation of Oleochemical 1,2-Diols to α-Hydroxyketones
Vu, N. D.; Guicheret, B.; Duguet, N.; Metay, E.; Lemaire, M. Green Chem. 2017, 19, 3390-3399.
DOI: 10.1039/c7gc00867h

Valorization of Madagascar's CNSL via the synthesis of one advanced intermediate (3-Pentadecylcyclohexanone).
Rahobinirina, Andrianarivo I.; Rakotondramanga, Maonja F.; Berlioz-Barbier, A.; Metay, E.; Ramanandraibe, V.; Lemaire, M. Tetrahedron Lett. 2017, 58, 2284-2289.
DOI:10.1016/j.tetlet.2017.04.093

Synthesis and biological evaluation of C-3 aliphatic coumarins as vitamin K antagonists.
Montagut-Romans, A.; Boulven, M.; Jacolot, M.; Moebs-Sanchez, S.; Hascoet, C.; Hammed, A.; Besse, S.; Lemaire, M.; Benoit, E.; Lattard, V.; Popowycz, F. Bioorg. Med. Chem. Lett. 2017, 27, 1598-1601.
DOI:10.1016/j.bmcl.2017.02.017

Hydrogen bonds prevent obtaining high molar mass PHUs.
Blain, M.; Cornille, A.; Boutevin, B.; Auvergne, R.; Andrioletti, B.; Caillol, S. J. Appl. Polym. Sci. 2017, 134, 44958-44970
DOI: 10.1002/app.44958

Synthesis, Surfactant Properties and Antimicrobial Activities of Methyl Glycopyranoside Ethers.
Belmessieri, D.; Gozlan, C.; Duclos, M.-C.; Molinier, V.; Aubry, J.-M.; Dumitrescu, O.; Lina, G.; Redl, A.; Duguet, N.; Lemaire, M. Eur. J. Med. Chem. 2017, 128, 98-106.
DOI: 10.1016/j.ejmech.2017.01.038

A study of cyclic carbonate aminolysis at room temperature: effect of cyclic carbonate structures and solvents on polyhydroxyurethane synthesis.
Cornille, A.; Blain, M.; Auvergne, R.; Andrioletti, B.; Boutevin, B.; Caillol, S. Polym. Chem. 2017, 8,592-604.
DOI: 10.1039/C6PY01854H

Urea- and Thiourea-Catalyzed Aminolysis of Carbonates.
Blain, M.; Yau, H.; Jean-Gérard, L.; Auvergne, R.; Benazet, D.; Schreiner, P. R.; Caillol, S.; Andrioletti, B. ChemSusChem, 2016, 9, 2269-2272.
DOI: 10.1002/cssc.201600778 

Solvo-surfactant properties of dialkyl glycerol ethers: Application as eco-friendly extractants of plant material through a novel Hydrotropic-Cloud-Point-Extraction (HCPE) process.
Lebeuf, R.; Illous, E.; Dussenne, C.; Molinier, V.; Da Silva, E.; Lemaire, M.; Aubry, J.-M. ACS Sustainable Chem. Eng. 2016, 4, 4815-4823.
DOI: 10.1021/acssuschemeng.6b01101 

Solvants verts.
Andrioletti, B. Tech. Ing. 2016, CHV4000 V1.

Reductive N-methylation of amines with calcium hydride and Pd/C catalyst.
Guyon, C.; Duclos, M.-C.; Metay, E.; Lemaire, M. Tetrahedron Lett. 2016, 57, 3002-3005.
DOI: 10.1016/j.tetlet.2016.05.094 

Synthesis of aminotelechelic prepolymers to circumvent the carbonation of amines in epoxy coatings.
Blain, M.; Jean-Gérard, L.; Benazet, D.; Boutevin, B.; Andrioletti, B.; Caillol, S. Macromol. Mater. Eng. 2016, 301, 682−693.
DOI: 10.1002/mame.201500402 

Synthesis of benzofuran derivatives as selective inhibitors of tissue-nonspecific alkaline phosphatase: effects on cell toxicity and osteoblast-induced mineralization.
Marques, S.; Buchet, R.; Popowycz, F.; Lemaire, M.; Mebarek, S. Bioorg. Med. Chem. Lett. 2016, 26, 1457-1459.
DOI: 10.1016/j.bmcl.2016.01.061 

C2 Arylated Benzo[b]thiophene Derivatives as Staphylococcus aureus NorA Efflux Pump Inhibitors.
Liger, F.; Bouhours, P.; Ganem-Elbaz, C.; Jolivalt, C.; Pellet-Rostaing, S.; Popowycz, F.; Paris, J.-M.; Lemaire, M. ChemMedChem 2016, 11, 320-330.
DOI: 10.1002/cmdc.201500463

Synthesis of P-stereogenic secondary phosphine oxides using α-d-glucosamine as a chiral precursor.
Copey, L.; Jean-Gérard, L.; Andrioletti, B.; Framery, E. Tetrahedron Lett. 2016, 57, 543-545.
DOI: 10.1016/j.tetlet.2015.12.074

3-Methylene-2,4-chromandione in situ trapping : Introducing molecular diversity on 4-hydroxycoumarin.
Montagut-Romans, A.; Boulven, M.; Lemaire, M.; Popowycz, F. RSC Adv. 2016, 6, 4540-4544.
DOI: 10.1039/C5RA22440C

Preparation of amphiphilic sorbitan monoethers through hydrogenolysis of sorbitan acetals and evaluation as bio-based surfactants.
Gozlan, C.; Deruer, E.; Duclos, M.-C.; Molinier, V.; Aubry, J.-M.; Redl, A.; Duguet, N.; Lemaire, M. Green Chem. 2016, 18, 1994-2004.
DOI: 10.1039/c5gc02131f

Novel access to N,N'-diaryl-trans-1,2-diaminocyclohexane ligands. A cheap and easy way to prepare ligand for asymmetric transfer hydrogenation.
El-Asaad, B.; Guicheret, B.; Métay, E.; Karame, I.; Lemaire, M. J. Mol. Catal. A: Chem. 2016, 411, 196-202.
DOI: 10.1016/j.molcata.2015.10.030

Dimethyl Sulfite a potential agent for methylation.
Mouselmani, R.; Da Silva, E.; Lemaire, M. Tetrahedron, 2015, 71, 8905-8910.
DOI: 10.1016/j.tet.2015.09.075

Bis-triazolyl BODIPYs: a simple dye with strong red-light emission.
Guérin, C.; Jean-Gérard, L.; Octobre, G.; Pascal, S.; Maury, O.; Pilet, G.; Ledoux, A.; Andrioletti, B. RSC. Adv. 2015, 5, 76342–76345.
DOI: 10.1039/C5RA14309H

D-Glucosamine as a novel chiral auxiliary for the stereoselective synthesis of P-stereogenic phosphine oxides.
D’onofrio, A.; Copey, L.; Jean-Gerard, L.; Goux-Henry, C.; Pilet, G.; Andrioletti, B.; Framery, E. Org. Biomol. Chem. 2015, 13, 9029-9034.
DOI: 10.1039/C5OB01323B

Glycerol Ether Synthesis: A Bench Test for Green Chemistry Concepts and Technologies.
Sutter, M.; Da Silva, E.; Duguet, N.; Raoul, Y.; Métay, E.; Lemaire, M. Chem. Rev. 2015, 115, 8609-8651.
DOI: 10.1021/cr5004002

Thiazolylidene-Catalyzed Cleavage of Methyl Oleate-Derived α-Hydroxy Ketone to the Corresponding Free Aldehydes.
Deruer, E.; Duguet, N.; Lemaire, M. ChemSusChem 2015, 8, 2481-2486.
DOI: 10.1002/cssc.201500462

Synthetic applications of hypophosphite derivatives in reduction.
Guyon, C.; Métay, E.; Popowycz, F.; Lemaire, M. Org. Biomol. Chem. 2015, 13, 7879-7906.
DOI: 10.1039/c5ob01032b

Reductive alkylation of active methylene compounds with carbonyl derivatives, calcium hydride and a heterogeneous catalyst.
Guyon, C.; Duclos, M.-C.; Sutter, M.; Métay, E.; Lemaire, M. Org. Biomol. Chem. 2015, 13, 7067-7075.
DOI: 10.1039/c5ob00849b

Experimental and theoretical investigations in the stereoselective synthesis of P-stereogenic phosphine oxides.
Copey, L.; Jean-Gerard, L.; Framery, E.; Pilet, G.; Robert, V.; Andrioletti, B. Chem. Eur. J. 2015, 21, 9057-9061.
DOI: 10.1002/chem.201501324 

H₂O₂-mediated Kraft lignin oxidation with readily available metal salts: what about the effect of ultrasound?
Napoly, F.; Kardos, N.; Jean-Gerard, L.; Goux-Henry, C.; Andrioletti, B.; Draye, M. Ind. Eng. Chem. Res. 2015, 54, 6046−6051.
DOI: 10.1021/acs.iecr.5b00595

A highly sustainable route to pyrrolidone derivatives – direct access to new biosourced solvents.
Ledoux, A.; Sandjong Kuigwa, L.; Framery, E; Andrioletti, B. Green Chem. 2015, 17, 3251-3254.
DOI: 10.1039/C5GC00417A

Fe(TAML)Li/tert-Butyl Hydroperoxide as a New Combination for Benzylic C-H Oxidation.
Napoly, F.; Kieffer, R..; Jean-Gerard, L.; Goux-Henry, C.; Draye, M.; Andrioletti, B. Tetrahedron Lett. 2015, 56, 2517-2520.
DOI: 10.1016/j.tetlet.2015.03.115

Chemically and Electrochemically Triggered Assembly of Viologen Radicals: Towards Multiaddressable Molecular Switches.
Kahlfuss, C.; Métay, E.; Duclos, M.-C.; Lemaire, M.; Milet, A.; Saint-Aman, E.; Bucher, C. Chem. — Eur. J. 2015, 21, 2090-2106.
DOI: 10.1002/chem.201405157

Reductive amination using a combination of CaH₂ and noble metal.
Guyon, C.; Da Silva, E.; Lafon, R.; Métay, E.; Lemaire, M. RSC Adv. 2015, 5, 2292-2298.
DOI: 10.1039/c4ra14808h

Catalytic reductive cleavage of methyl a-D-glucoside acetals to ethers using hydrogen as a clean reductant.
Gozlan, C.; Lafon, R.; Duguet, N.; Redl, A.; Lemaire, M. RSC Adv. 2014, 4, 50653-50661.
DOI: 10.1039/c4ra09350j

Identification of VKORC1 genotype leading to resistance to tecarfarin.
Matagrin, B.; Montagut-Romans, A.; Damin, M.; Lemaire, M.; Popowycz, F.; Benoit, E.; Lattard, V. J. Clin. Pharmacol. 2014, 54, 896-900.
DOI: 10.1002/jcph.332

Rational investigations in the ring opening of cyclic carbonates by amines.
Blain, M.; Jean-Gerard, L.; Auvergne, R.; Benazet, D.; Caillol, S.; Andrioletti, B. Green Chem. 2014, 16, 4286-4291.
DOI: 10.1039/C4GC01032A 

Synthesis, solid-state analyses, and anion-binding properties of meso-aryldipyrrin-5,5'-diylbis(phenol) and -bis(aniline) ligands.
Copey, L.; Jean-Gerard, L.; Framery, E.; Pilet, G.; Andrioletti, B. Eur. J. Org. Chem. 2014, 4759-4766.
DOI: 10.1002/ejoc.201402446 

Amidation of phenol derivatives: a direct synthesis of paracetamol (acetaminophen) from hydroquinone.
Joncour, R.; Duguet, N.; Métay, E.; Ferreira, A.; Lemaire, M. Green Chem. 2014, 16, 2997-3002.
DOI: 10.1039/c4gc00166d 

Green, selective and swift oxidation of cyclic alcohols to corresponding ketones.
Chatel, G.; Monnier, C.; Kardos, N.; Voiron, C.; Andrioletti, B.; Draye, M. Applied Catal., A 2014, 478, 157-164.
DOI: 10.1016/j.apcata.2014.03.033 

Novel Hybrid Materials on the Basis of Nanostructured Tin Dioxide and a Lipase from Rhizopus delemar with Improved Enantioselectivity.
Guncheva, M.; Dimitrov, M.; Napoly, F.; Draye, M.; Andrioletti, B. J. Mol. Catal. B 2014, 102, 72-80.
DOI: 10.1016/j.molcatb.2014.01.017 

Reversible dimerization of viologen radicals covalently linked to a calixarene platform: Experimental and theoretical aspects.
Kahlfuss, C.; Métay, E.; Duclos, M.-C.; Lemaire, M.; Oltean, M.; Milet, A.; Saint-Aman, E.; Bucher, C. C. R. Chim. 2014, 17, 505-511.
DOI: 10.1016/j.crci.2014.01.006 

Commutative reduction of aromatic ketones to arylmethylenes/alcohols by hypophosphites catalyzed by Pd/C under biphasic conditions.
Guyon, C.; Baron, M.; Lemaire, M.; Popowycz, F.; Métay, E. Tetrahedron 2014, 70, 2088-2095.
DOI: 10.1016/j.tet.2014.02.014 

Straightforward access to cyclic amines by dinitriles reduction.
Laval, S.; Dayoub, W.; Pehlivan, L.; Métay, E.; Favre-Reguillon, A.; Delbrayelle, D.; Mignani, G.; Lemaire, M. Tetrahedron 2014, 70, 975-983.
DOI: 10.1016/j.tet.2013.11.101 

Fe(TAML)Li/(diacetoxyiodo)benzene-Mediated Oxidation of Alcohols: Evidence for Mild and Selective C–O and C–C Oxidative Cleavage in Lignin Model Transformations.
Napoly, F.; Jean-Gérard, L.; Goux-Henry, C.; Draye, M.; Andrioletti, B. Eur. J. Org. Chem. 2014, 781–787.
DOI: 10.1002/ejoc.201301093 

Reduction of nitriles into aldehydes using a TMDS/V(O)(OiPr)₃ reducing system.
Laval, S.; Dayoub, W.; Pehlivan, L.; Métay, E.; Delbrayelle, D.; Mignani, G.; Lemaire, M., Tetrahedron Lett. 2014, 55, 23-26.
DOI: 10.1016/j.tetlet.2013.10.065
Highlighted in Organic Chemistry Portal: Taber, D. F. Org. Chem. Highlights 2015, March 23.
http://www.organic-chemistry.org/Highlights/2015/23March.shtm

Inhibitors of tissue-nonspecific alkaline phosphatase: Design, synthesis, kinetics, biomineralization and cellular tests.
Debray, J.; Chang, L.; Marques, S.; Pellet-Rostaing, S.; Le Duy, D.; Mebarek, S.; Buchet, R.; Magne, D.; Popowycz, F.; Lemaire, M. Bioorg. Med. Chem. 2013, 21, 7981-7987.
DOI: 10.1016/j.bmc.2013.09.053

1,2,3-Trimethoxypropane, a glycerol-based solvent with low toxicity: new utilization for the reduction of nitrile, nitro, ester, and acid functional groups with TMDS and a metal catalyst.
Sutter, M.; Pehlivan, L.; Lafon, R.; Dayoub, W.; Raoul, Y.; Métay, E.; Lemaire, M. Green Chem. 2013, 15, 3020-3026.
DOI: 10.1039/c3gc41082j

New boron-containing molybdenum imido alkylidene complexes for linear olefin homometathesis.
Nasr, A.; Breuil, P.-A. R.; Silva, D. C.; Berthod, M.; Dellus, N.; Jeanneau, E.; Lemaire, M.; Olivier-Bourbigou, H. Organometallics 2013, 32, 5320-5325.
DOI: 10.1021/om400577k

Straightforward solvent-free heterogeneous palladium-catalyzed synthesis of arylamines from nonaromatic substrates by dehydrogenative alkylation.
Sutter, M.; Duclos, M.-C.; Guicheret, B.; Raoul, Y.; Métay, E.; Lemaire, M. ACS Sustainable Chem. Eng. 2013, 1, 1463-1473.
DOI: 10.1021/sc4002164

Heterogeneous Palladium-Catalyzed Synthesis of Aromatic Ethers by Solvent-Free Dehydrogenative Aromatization: Mechanism, Scope, and Limitations Under Aerobic and Non-Aerobic Conditions.
Sutter, M.; Lafon, R.; Raoul, Y.; Métay, E.; Lemaire, M. Eur. J. Org. Chem. 2013, 26, 5902-5916.
DOI: 10.1002/ejoc.201300485

1,2,3-Trimethoxypropane and Glycerol Ethers as Biosource Solvents from Glycerol. Synthesis by Solvent-Free Phase-Transfer Catalysis and Utilization as an Alternative Solvent in Chemical Transformations.
Sutter, M.; Dayoub, W.; Métay, E.; Raoul, Y.; Lemaire, M. ChemCatChem 2013, 5, 2893-2904.
DOI: 10.1002/cctc.201300458

One-pot, solvent-free access to unsymmetrical ureas by palladium-catalyzed reductive alkylation using molecular hydrogen.
Mohy El Dine, T.; Chapron, S.; Duclos, M.-C.; Duguet, N.; Popowycz, F.; Lemaire, M. Eur. J. Org. Chem. 2013, 24, 5445-5454.
DOI: 10.1002/ejoc.201300642

Hydrotropic Properties of Alkyl and Aryl Glycerol Monoethers.
Moity, L.; Shi, Y.; Molinier, V.; Dayoub, W.; Lemaire, M.; Aubry, J.-M. J. Phys. Chem. B 2013, 117, 9262-9272.
DOI: 10.1021/jp403347u

Biphasic glycerol/2-methyltetrahydrofuran, ruthenium-catalyzed enantio-selective transfer hydrogenation of ketones using sodium hypophosphite as hydrogen donor.
Guyon, C.; Métay, E.; Duguet, N.; Lemaire, M. Eur. J. Org. Chem. 2013, 24, 5439-5444.
DOI: 10.1002/ejoc.201300506

Redox control of molecular motions in bipyridinium appended calixarenes.
Iordache, A.; Kannappan, R.; Métay, E.; Duclos, M.-C.; Pellet-Rostaing, S.; Lemaire, M.; Milet, A.; Saint-Aman, E.; Bucher, C. Org. Biomol. Chem. 2013, 11, 4383-4389.
DOI: 10.1039/c3ob40356d

Unraveling the Catalytic Cycle of Tertiary Phosphine Oxides Reduction with Hydrosiloxane and Ti(OiPr)₄ through EPR and ²⁹Si NMR Spectroscopy.
Petit, C.; Poli, E.; Favre-Reguillon, A.; Khrouz, L.; Denis-Quanquin, S.; Bonneviot, L.; Mignani, G.; Lemaire, M. ACS Catal. 2013, 3, 1431-1438.
DOI: 10.1021/cs4002767

Conformational Plasticity of Hydrogen Bonded Bis-Urea Supramolecular Polymers.
Brocorens, P.; Linares, M. ; Duhayon, C.; Guillot, R.; Andrioletti, B. ; Dominique, S.; Isare, B.; Lazzaroni, R.; Bouteiller, L. J. Phys. Chem. B 2013, 117, 5379-5386.
DOI: 10.1021/jp401915y

Reduction of aromatic and aliphatic nitro groups to anilines and amines with hypophosphites associated with Pd/C.
Baron, M.; Métay, E.; Lemaire, M.; Popowycz, F. Green Chem. 2013, 15, 1006-1015.
DOI: 10.1039/c3gc37024k

1-O-Alkyl (di)glycerol ethers synthesis from methyl esters and triglycerides by two pathways: catalytic reductive alkylation and transesterification/reduction.
Sutter, M.; Dayoub, W.; Métay, E.; Raoul, Y.; Lemaire, M. Green Chem. 2013, 15, 786-797.
DOI: 10.1039/c3gc36907b

Straightforward synthesis of 2-acetyl-substituted benzo[b]thiophenes.
Debray, J.; Lemaire, M.; Popowycz, F. Synlett 2013, 24, 37-40.
DOI: 10.1055/s-0032-1317674

New research areas inspired by sustainable development.
Da Silva, E.; Dayoub, W.; Duguet, N.; Métay, E.; Popowycz, F.; Lemaire, M. C. R. Chim. 2013, 16, 343-349.
DOI: 10.1016/j.crci.2012.12.019

Straightforward heterogeneous palladium catalyzed synthesis of aryl ethers and aryl amines via a solvent free aerobic and non-aerobic dehydrogenative arylation.
Sutter, M.; Sotto, N.; Raoul, Y.; Métay, E.; Lemaire, M. Green Chem. 2013, 15, 347-352.
DOI: 10.1039/c2gc36776a

Hydrophobic bis(trifluoromethylsulfonyl)imide based ionic liquids pyrolysis: through the window of the ultrasonic reactor
Chatel, G.; Pflieger, R.; Naffrechoux, E.; Nikitenko, S.I.; Suptil, J.; Goux-Henry, C.; Kardos, N.; Andrioletti, B.; Draye, M. ACS Sustainable Chem. Eng. 2013, 1, 137-143.
DOI: 10.1021/sc300068d

Ultrasonic Properties of Hydrophobic Bis(trifluoromethylsulfonyl)imide-Based Ionic Liquids.
Chatel, G.; Leclerc, L.; Naffrechoux, E.;  Bas, C.; Kardos, N. ; Goux-Henry, C.; Andrioletti, B.; Draye, M. J. Chem. Eng. Data 2012, 57, 3385-3390.
DOI: 10.1021/je300377a

Utiliser de l’eau pour oxyder et produire du courant ?
Aukauloo, A.; Andrioletti, B. La lettre d’info des Instituts du CNRS, 20/11/2012, http://www.cnrs.fr/endirectdeslabos/lettre.php?modele_lettre=2&numero=90

Functionalization of BINOL and application in the homo- and heterogeneous enantioselective epoxidation of a,b-unsaturated ketones.
El Kadiri, M.Y.; Framery, E.; Andrioletti, B. Tetrahedron Lett. 2012, 53, 6335–6338.
DOI: 10.1016/j.tetlet.2012.09.004

Highlighted in Synfacts: Lanthanides-Catalyzed Enantioselective Epoxidation of a,b-Unsaturated Ketones
El Kadiri, M.Y.; Framery, E.; Andrioletti, B. Synfacts 2013, 9, 0191.
DOI: 10.1055/s-0032-1318024

Chemical Activation of a Mononuclear Non-Porphyrinic Manganese Complex using Water as Oxygen Source for Oxygen Atom Transfer Reaction.
El Kadiri, M.Y.; El Ghachtouli, S.; Guillot, R.; Billon, L.; Charlot, M-F.; Framery, E.; Andrioletti, B.; Aukauloo, A. ChemSusChem 2012, 5, 2147-2150.
DOI: 10.1002/cssc.201200440

Propylene carbonate synthesis from propylene glycol, carbon dioxide and benzonitrile by alkali carbonate catalysts.
Da Silva, E.; Dayoub, W.; Mignani, G.; Raoul, Y.; Lemaire, M. Catal. Commun. 2012, 29, 58-62.
DOI: 10.1016/j.catcom.2012.08.030

Synthesis and evaluation of P-chirogenic monodentate binaphthyl phosphines.
Duclos, M.-C.; Singjunla, Y.; Petit, C.; Favre-Reguillon, A.; Jeanneau, E.; Popowycz, F.; Métay, E.; Lemaire, M. Tetrahedron Lett. 2012, 53, 5984-5986.
DOI: 10.1016/j.tetlet.2012.07.136

Selective Synthesis of 1-O-Alkyl(poly)glycerol Ethers by Catalytic Reductive Alkylation of Carboxylic Acids with a Recyclable Catalytic System.
Sutter, M.; Dayoub, W.; Métay, E.; Raoul, Y.; Lemaire, M. ChemSusChem 2012, 5, 2397-2409.
DOI: 10.1002/cssc.201200447

D-Glucosamine based-phosphine for Suzuki-Miyaura cross-coupling reactions in the supported aqueous phase catalysis system.
Wojcik, K.; Goux-Henry, C.; Andrioletti, B.; Pietrusiewicz, M. K.; Framery, E. Tetrahedron Lett. 2012, 53, 5602–5604.
DOI: 10.1016/j.tetlet.2012.07.138

Highlighted in Synfacts: Suzuki coupling with a supported Pd-glucosamine phosphine complex.
Wojcik, K.; Goux-Henry, C.; Andrioletti, B.; Pietrusiewicz, M.K.; Framery, E. Synfacts 2012, 8, 1379.
DOI: 10.1055/s-0032-1317641

Synthesis of 3-Substituted Tetrahydrofuran and 4-Substituted Tetrahydropyran Derivatives by Cyclization of Dicarboxylic Acids with InBr₃/TMDS.
Pehlivan, L.; Métay, E.; Delbrayelle, D.; Mignani, G.; Lemaire, M. Eur. J. Org. Chem. 2012, 25, 4689-4693.
DOI: 10.1002/ejoc.201200727

Copper(II) triflate-catalyzed reduction of carboxylic acids to alcohols and reductive etherification of carbonyl compounds.
Zhang, Y.-J.; Dayoub, W.; Chen, G.-R.; Lemaire, M. Tetrahedron 2012, 68, 7400-7407.
DOI: 10.1016/j.tet.2012.06.080

H₂O₂/NaHCO₃-mediated enantioselective epoxidation of olefins in NTf₂-based ionic liquids and under ultrasound.
Chatel, G.; Goux-Henry , C., Mirabaud, A.; Rossi, T.; Kardos, N.; Andrioletti, B.; Draye, M. J. Catal. 2012, 291, 127-132.
DOI: 10.1016/j.jcat.2012.04.016

Enantioselective straightforward access to benzo[b]thiophene analogs of Azatoxin.
Gracia, S.; Marion, C.; Rey, J.; Popowycz, F.; Pellet-Rostaing, S.; Lemaire, M. Tetrahedron Lett. 2012, 53, 3165-3168.
DOI: 10.1016/j.tetlet.2012.04.055

An Improved and Safer Synthesis of (R)- and (S)-4,4'-Diaminomethyl-BINAP.
Dayoub, W.; Favre-Reguillon, A.; Berthod, M.; Jeanneau, E.; Mignani, G.; Lemaire, M. Eur. J. Org. Chem. 2012, 16, 3074-3078.
DOI: 10.1002/ejoc.201200219

Reduction of phosphine oxides to phosphines with the InBr₃/TMDS system.
Pehlivan, L.; Métay, E.; Delbrayelle, D.; Mignani, G.; Lemaire, M. Tetrahedron 2012, 68, 3151-3155.
DOI: 10.1016/j.tet.2012.02.063

TMDS as a Dual-Purpose Reductant in the Regioselective Ring Cleavage of Hexopyranosyl Acetals to Ethers.
Zhang, Y.-J.; Dayoub, W.; Chen, G.-R.; Lemaire, M. Eur. J. Org. Chem. 2012, 10, 1960-1966.
DOI: 10.1002/ejoc.201101682

Solvent-Free Michael Addition to Non-protected 3-(2-Nitrovinyl)indole by Ultrasound Activation.
Baron, M.; Métay, E.; Lemaire, M.; Popowycz, F. J. Org. Chem. 2012, 77, 3598-3603.
DOI: 10.1021/jo2026096

EDTA and DTPA modified ligands as sequestering agents for uranyl decorporation.
Leydier, A.; Lin, Y.; Arrachart, G.; Turgis, R.; Lecercle, D.; Favre-Reguillon, A.; Taran, F.; Lemaire, M.; Pellet-Rostaing, S. Tetrahedron 2012, 68, 1163-1170.
DOI: 10.1016/j.tet.2011.11.065

Ultrasound and ionic liquid: an efficient combination for tuning the mechanism of alkene epoxidation.
Chatel, G.; Goux-Henry, C.; Kardos, N.; Suptil, J.; Andrioletti, B.; Draye, M. Ultrason. Sonochem. 2012, 19, 390–394.
DOI: 10.1016/j.ultsonch.2011.10.007

Environmentally benign metal triflate-catalyzed reductive cleavage of the C-O bond of acetals to ethers.
Zhang, Y.-J.; Dayoub, W.; Chen, G.-R.; Lemaire, M. Green Chem. 2011, 13, 2737-2742.
DOI: 10.1039/c1gc15636e

Reduction of Aromatic and Aliphatic Esters- Using the Reducing Systems MoO₂(acac)₂ or V(O)(OiPr)₃ in Combination with 1,1,3,3-Tetramethyldisiloxane.
Pehlivan, L.; Métay, E.; Laval, S.; Dayoub, W.; Delbrayelle, D.; Mignani, G.; Lemaire, M. Eur. J. Org. Chem. 2011, 36, 7400-7406.
DOI: 10.1002/ejoc.201101016

Oxidative nucleophilic substitution: transformation of alkylboronic derivatives.
Cazorla, C.; Métay, E.; Lemaire, M. Tetrahedron 2011, 67, 8615-8621.
DOI:  10.1016/j.tet.2011.09.055

Dipyrrinphenol–Mn(III) complex: synthesis, electrochemistry, spectroscopic characterisation and reactivity.
El Ghachtouli, S.; Wojcik, K.; Copey, L.; Szydlo, F.; Framery, E.; Goux-Henry, C.; Billon, L.; Charlot, M.-F.; Guillot, R.; Andrioletti, B.; Aukauloo, A. Dalton Trans. 2011, 40, 9090-9093.
DOI: 10.1039/C1DT10868A

O-Alkylation of phenol derivatives via a nucleophilic substitution.
Cazorla, C.; Pfordt, E.; Duclos, M.-C.; Métay, E.; Lemaire, M. Green Chem. 2011, 13, 2482-2488.
DOI: 10.1039/c1gc15481h

Deux exemples de “chimie éco-responsible”.
Métay, E.; Dayoub, W.; Andrioletti, B.; Lemaire, M. Actual. Chim. 2011, 353-354, 21-24.

Direct arylation: Alternative to classic cross-coupling chemistry and a fruitful synthetic tool for the access to novative bioactive molecules.
Popowycz, F.; Métay, E.; Lemaire, M. C. R. Chim. 2011, 14, 621-628.
DOI: 10.1016/j.crci.2010.06.006

Hydrosiloxane-Ti(OiPr)₄: an efficient system for the reduction of primary amides into primary amines as their hydrochloride salts.
Laval, S.; Dayoub, W.; Pehlivan, L.; Métay, E.; Favre-Reguillon, A.; Delbrayelle, D.; Mignani, G.; Lemaire, M. Tetrahedron Lett. 2011, 52, 4072-4075.
DOI: 10.1016/j.tetlet.2011.05.109

Sequestering agent for uranyl chelation: new binaphtyl ligands.
Leydier, A.; Lecercle, D.; Pellet-Rostaing, S.; Favre-Reguillon, A.; Taran, F.; Lemaire, M. Tetrahedron Lett. 2011, 52, 3973-3977.
DOI: 10.1016/j.tetlet.2011.05.075

A New Solvent-Free Reaction for the Preparation of Alkoxysilane from Cyclic Ethers, Alcohols, or Carbonyl Compounds.
Pehlivan, L.; Métay, E.; Boyron, O.; Demonchaux, P.; Mignani, G.; Lemaire, M. Eur. J. Org. Chem. 2011, 24, 4687-4692.
DOI: 10.1002/ejoc.201100489

Bromination of 3-substituted benzo[b]thiophenes: access to raloxifen intermediate.
Liger, F.; Pellet-Rostaing, S.; Popowycz, F.; Lemaire, M. Tetrahedron Lett. 2011, 52, 3736-3739.
DOI: 10.1016/j.tetlet.2011.05.043

Synthesis and evaluation of thiophenyl derivatives as inhibitors of alkaline phosphatase.
Chang, L.; Duy, D. L.; Mebarek, S.; Popowycz, F.; Pellet-Rostaing, S.; Lemaire, M.; Buchet, R. Bioorg. Med. Chem. Lett. 2011, 21, 2297-2301.
DOI: 10.1016/j.bmcl.2011.02.089

TMDS-Pd/C: a convenient system for the reduction of acetals to ethers.
Shi, Y.; Dayoub, W.; Chen, G.-R.; Lemaire, M. Tetrahedron Lett. 2011, 52, 1281-1283.
DOI: 10.1016/j.tetlet.2011.01.038

Alternative method for the reduction of aromatic nitro to amine using TMDS-iron catalyst system.
Pehlivan, L.; Métay, E.; Laval, S.; Dayoub, W.; Demonchaux, P.; Mignani, G.; Lemaire, M. Tetrahedron 2011, 67, 1971-1976.
DOI: 10.1016/j.tet.2010.12.070

Investigations providing a plausible mechanism in the hexamethyldisilazane-catalyzed trimerization of alkyl isocyanates.
Roman, M.; Andrioletti, B.; Lemaire, M.; Bernard, J.-M.; Schwartz, J.; Barbeau, P. Tetrahedron 2011, 67, 1506-1510.
DOI: 10.1016/j.tet.2010.12.013

Selective synthesis of 1-O-alkyl glycerol and diglycerol ethers by reductive alkylation of alcohols.
Shi, Y.; Dayoub, W.; Chen, G.-R.; Lemaire, M. Green Chem. 2010, 12, 2189-2195.
DOI: 10.1039/c0gc00202j

Supramolecular Balance: Using Cooperativity To Amplify Weak Interactions.
Roman, M.; Cannizzo, C.; Pinault, T.; Isare, B.; Andrioletti, B.; van der Schoot, P.; Bouteiller, L. J. Am. Chem. Soc. 2010, 132, 16818–16824.
DOI: 10.1021/ja105717u

Straightforward synthesis of indolizidine alkaloid 167B.
Gracia, S.; Jerpan, R.; Pellet-Rostaing, S.; Popowycz, F.; Lemaire, M. Tetrahedron Lett. 2010, 51, 6290-6293.
DOI: 10.1016/j.tetlet.2010.09.105

Synthesis of (±)-phthalascidin 650 analogue: new synthetic route to (±)-phthalascidin 622.
Razafindrabe, C. R.; Aubry, S.; Bourdon, B.; Andriantsiferana, M.; Pellet-Rostaing, S.; Lemaire, M. Tetrahedron 2010, 66, 9061-9066.
DOI: 10.1016/j.tet.2010.08.053

Chain stopper engineering for hydrogen bonded supramolecular polymers.
Pinault, T.; Andrioletti, B.; Bouteiller, L. Beilstein J. Org. Chem. 2010, 6, 869–875.
DOI: 10.3762/bjoc.6.102

One-step selective synthesis of branched 1-O-alkyl-glycerol/diglycerol monoethers by catalytic reductive alkylation of ketones.
Shi, Y.; Dayoub, W.; Chen, G.-R.; Lemaire, M. Sci. China: Chem. 2010, 53, 1953-1956.
DOI: 10.1007/s11426-010-4054-4

Selective Adsorption of Neutral Nitrogen Compounds from Fuel Using Ion-Exchange Resins.
Xie, L.-L.; Favre-Reguillon, A.; Wang, X.-X.; Fu, X.; Lemaire, M. J. Chem. Eng. Data 2010, 55, 4849-4853.
DOI: 10.1021/je100446p

Recent progress in homogeneous supported asymmetric catalysis: example of the BINAP and the BOX ligands.
Framery, E.; Andrioletti, B.; Lemaire, M. Tetrahedron: Asymm. 2010, 21, 1110-1124.
DOI: 10.1016/j.tetasy.2010.04.028

Viologen-based redox-switchable anion-binding receptors.
Kannappan, R.; Bucher, C.; Saint-Aman, E.; Moutet, J.-C.; Milet, A.; Oltean, M.; Métay, E.; Pellet-Rostaing, S.; Lemaire, M.; Chaix, C. New J. Chem. 2010, 34, 1373-1386.
DOI: 10.1039/b9nj00417c

Water solubilization of xanthene dyes by post-synthetic sulfonation in organic media.
Romieu, A.; Tavernier-Lohr, D.; Pellet-Rostaing, S.; Lemaire, M.; Renard, P.-Y. Tetrahedron Lett. 2010, 51, 3304-3308.
DOI: 10.1016/j.tetlet.2010.04.080

A mild titanium-based system for the reduction of amides to aldehydes.
Laval, S.; Dayoub, W.; Favre-Reguillon, A.; Demonchaux, P.; Mignani, G.; Lemaire, M. Tetrahedron Lett. 2010, 51, 2092-2094.
DOI: 10.1016/j.tetlet.2010.02.008
Highlighted in Organic Chemistry Portal: Taber, D. F. Org. Chem. Highlights 2010, October 25.
http://www.organic-chemistry.org/Highlights/2010/25October.shtm

Iron-catalyzed selective reduction of nitro compounds to amines.
Pehlivan, L.; Métay, E.; Laval, S.; Dayoub, W.; Demonchaux, P.; Mignani, G.; Lemaire, M. Tetrahedron Lett. 2010, 51, 1939-1941.
DOI: 10.1016/j.tetlet.2010.01.067

Stereochemistry effect of dicyclohexano-18-crown-6 on zinc isotope separation.
Lin, Y.; Espinas, J.; Pellet-Rostaing, S.; Favre-Reguillon, A.; Lemaire, M. New J. Chem. 2010, 34, 388-390.
DOI: 10.1039/b9nj00417c

A straightforward synthesis of unsymmetrical secondary phosphine boranes.
Petit, C.; Favre-Reguillon, A.; Mignani, G.; Lemaire, M. Green Chem. 2010, 12, 326-330.
DOI: 10.1039/b920324a

Separation of lanthanides(III) by inorganic nanofiltration membranes using a water soluble complexing agent.
Borrini, J.; Bernier, G.; Pellet-Rostaing, S.; Favre-Reguillon, A.; Lemaire, M. J. Membr. Sci. 2010, 348, 41-46.
DOI: 10.1016/j.memsci.2009.10.034